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131.
We study the importance of the zones of weakness and the pattern of downgoing flow in steady-state models of subducting lithosphere, which interacts mechanically and thermally with the ambient mantle. The non-linear system of governing equations consists of (i) the momentum equation in stream function formulation and (ii) the steady-state heat transfer equation including conduction and advection of heat and dissipation. A finite element method has been applied to this system. We consider the viscosity to be a non-linear function of both the temperature and the stream function. In steady-state two-dimensional (2D) flow, the stream function isolines follow material trajectories. They are used to follow the top of the subducting slab, which because of its possible increase in water content, is assumed to have a lower viscosity. The zone of weakness has been thus obtained in the self-consistent fashion since the stream function as well as the temperature are the output from our modeling and no a priori assumptions about the shape of the bending lithosphere are taken into account. It was shown that several orders decrease of viscosity in the zone of weakness is required to obtain the dip angle of about 45°. If the decrease of viscosity is not sufficient enough, the subducted slab either sinks almost vertically or does not exhibit a plate-like behavior. We have also demonstrated that shear heating can unrealistically increase at the zone of weakness for fast subductions if decrease of viscosity is underestimated.  相似文献   
132.
Stable sulfur isotope fractionation during microbial sulfate reduction is a potential tool to estimate sulfate reduction rates at field sites. However, little is known about the influence of the utilized carbon source on the magnitude of sulfur isotope fractionation. To investigate this effect, both a pure culture (strain PRTOL1) and enrichment cultures from a petroleum hydrocarbon (PHC)-contaminated aquifer were used and grown in batch cultures on various carbon sources with an initial sulfate concentration of 1 mmol/L. As sole carbon sources the PHC components naphthalene, 1,3,5-trimethylbenzene, and heating oil (enrichment culture) and the organic acids acetate, pyruvate, benzoate, and 3-phenylpropionate (enrichment culture and PRTOL1) were used. Sulfate reduction rates of all cultures ranged from 6 ± 1 nmol cm−3 d−1 (enrichment culture grown on 1,3,5-trimethylbenzene) to 280 ± 6 nmol cm−3 d−1 (enrichment culture grown on pyruvate). Cell-specific sulfate reduction rates ranged from 1.1 × 10−14 mol cell−1 d−1 (PRTOL1 grown on pyruvate) to 1.5 × 10−13 mol cell−1 d−1 (PRTOL1 grown on acetate). Sulfur isotope enrichment factors (ε) for the enrichment culture ranged from 16.1‰ (3-phenylpropionate) to 34.5‰ (1,3,5-trimethylbenzene) and for PRTOL1 from 30.0‰ (benzoate) to 36.0‰ (pyruvate). Cultures of PRTOL1 always showed higher ε values than the enrichment culture when grown on the same carbon source due to culture-specific properties. Higher ε values were obtained when the enrichment culture was grown on PHC components than on organic acids. No relationship between ε values and cell-specific sulfate reduction rate existed when all data were combined. When comparing the magnitude of ε values determined in this laboratory study with ε values measured at contaminated and uncontaminated field sites, it becomes evident that a multitude of factors influences ε values at field sites and complicates their interpretation. The results of this study help us assess some of the general parameters that govern the magnitude of ε in sulfate-reducing environments.  相似文献   
133.
Martin Jones  Rhys Jones 《Geoforum》2004,35(4):409-424
After a period of considerable and sustained hegemony, many commentators have argued that contemporary processes of globalisation are acting as a challenge to nation state sovereignty. The paper argues that geographers need to focus on the ways in which the nation state continues to act, albeit in a modified manner, within the era of globalisation. This might help to position geography within globalisation debates, which--according to Dicken [Geographers and `globalization': (yet) another missed boat? forthcoming, Transactions of the Institute of British Geographers, 2004]--we have not been centrally involved in. Drawing on the work of Michael Mann, we focus on a neglected dimension of state power--namely, its ideological form--as a means of exploring how the nation state is being differentially re-engineered under globalisation. Using Mann's classification of forms of ideological organisation, we deploy three vignettes in order to demonstrate the evolving nature of ideological power within the contemporary UK State.  相似文献   
134.
We have developed a significant body of new field-based evidence relating to the history of crustal extension in western Turkey. We establish that two of the NE–SW-trending basins in this region, the Gördes and Selendi Basins, whose sedimentary successions begin in the early Miocene, are unlikely to relate to late-stage Alpine compressional orogeny or to E–W extension of Tibetan-type grabens as previously suggested. We argue instead that these basins are the result of earlier (?) late Oligocene, low-angle normal faulting that created approximately N–S “scoop-shaped” depressions in which clastic to lacustine and later tuffaceous sediments accumulated during early–mid-Miocene time, separated by elongate structural highs. These basins were later cut by E–W-trending (?) Plio–Quaternary normal faults that post-date accumulation of the Neogene deposits. In addition, we interpret the Alaşehir (Gediz) Graben in terms of two phases of extension, an early phase lasting from the early Miocene to the (?) late Miocene and a young Plio–Quaternary phase that is still active. Taking into account our inferred earlier phase of regional extension, we thus propose a new three-phase “pulsed extension” model for western Turkey. We relate the first two phases to “roll-back” of the south Aegean subduction zone and the third phase to the westward “tectonic escape” of Anatolia.  相似文献   
135.
136.
The oldest known bona fide succession of clastic metasediments occurs in the Isua Greenstone Belt, SW Greenland and consists of a variety of mica schists and rare metaconglomerates. The metasediments are in direct contact with a felsic metavolcanic lithology that has previously been dated to 3.71 Ga. Based on trace element geochemical data for > 30 metasediments, we selected the six samples with highest Zr concentrations for zircon extraction. These samples all yielded very few or no zircon. Those extracted from mica schists yielded ion probe U/Pb ages between 3.70 and 3.71 Ga. One metaconglomerate sample yielded just a single zircon of 3.74 Ga age.The mica schist hosted zircons have U/Pb ages, Th / U ratios, REE patterns and Eu anomalies indistinguishable from zircon in the adjacent 3.71 Ga felsic metavolcanic unit. Trace element modelling requires the bulk of material in the metasediments to be derived from variably weathered mafic lithologies but some metasediments contain substantial contribution from more evolved source lithologies. The paucity of zircon in the mica schists is thus explained by incorporation of material from largely zircon-free volcanic lithologies. The absence of older zircon in the mica schists and the preponderance of mafic source material imply intense, mainly basaltic resurfacing of the early Earth. The implications of this process are discussed.Thermal considerations suggest that horizontal growth of Hadean crust by addition of mafic-ultramafic lavas must have triggered self-reorganisation of the protocrust by remelting. Reworking of Hadean crust may have been aided by burial of hydrated (weathered) metabasalt due to semi-continuous addition of new voluminous basalt outpourings. This process causes a bias towards eruption of Zr-saturated partial melts at the surface with O-isotope compositions potentially different from the mantle. The oldest zircons hosted in sediments would have been buried to substantial depth or formed in plutons that crystallised at some depth, from which it took hundreds of millions of years for them to be exhumed and incorporated into much younger sediments.  相似文献   
137.
138.
Clinopyroxenes from pyroxenite, ijolite and nepheline syenite from the main intrusion of the Alnö complex define two sub-parallel compositional trends with respect to Na, Ca and FeTOT plotted against alkali-pyroxene fractionation index (Na–Mg). Both trends define a smooth fractionation of increasing Na and FeTOT and decreasing Ca with increasing Na–Mg, but one set of samples contain clinopyroxenes that constantly plot at higher Na and lower FeTOT and Ca (at similar Na–Mg) than the rest of the samples. Clinopyroxenes with higher Ca and FeTOT and lower Na (trend 1) co-exist with substantial amounts of Ti-andradite (up to 70 vol.%), while the sample set defining the more Na-rich trend (trend 2) lack co-existing Ti-andradite. Clinopyroxenes from both trends show fractionated REE patterns with a distinct difference in HREE content, reflecting the content of co-existing Ti-andradite. The rocks of the first Ti-andradite-bearing trend crystallized slightly prior to the rocks of the second trend, probably from a primitive, Ca- and Ti-rich nephelinitic magma. Crystallisation of pyroxenite and melteigite occurred under low aSiO2 and high aCaO and aTiO2 as evidenced by the presence of perovskite and sometimes substantial amounts of magnetite. Subsequent increase in aSiO2 is evidenced in the overgrowth of perovskite by titanite, which in turn is overgrown by Ti-andradite. Nepheline syenitic residuals crystallized under higher aSiO2 and aNa2O and lower aCaO and aTiO2, which reduced Ti-andradite into an accessory phase and produced more Si- and Na-rich clinopyroxenes. Some of these residuals probably also mixed with new primitive magma producing a hybrid magma that crystallised the more Na-rich and Ca- and FeTOT-poor clinopyroxenes of trend 2. The complete lack of Ti-andradite in these rocks indicates different crystallisation conditions and also a different magma composition.  相似文献   
139.
140.
Experiments of Zn2+ and Fe3+ coprecipitation as a function of pH were conducted in the laboratory at ambient temperature and pressure. X-ray diffraction patterns of the coprecipitates show two broad peaks at 0.149 and 0.258 nm, which is consistent with published patterns for pure 2-line ferrihydrite. Zn2+ uptake occurred at pH ≥5 while Fe3+ precipitation occurred between pH 3 and 4, although both Zn2+ and Fe3+ were present in the same solution during the entire range of pH titration. High-resolution transmission electron microscopy shows that the coprecipitates are 2 to 6 nm sized single crystalline particles but aggregated to 50 to 400 nm sized clusters. Analytical electron microscopy indicated that the 5% atomic Zn with respect to Fe was homogeneously distributed. No segregated phases were found in the clusters or at single crystal edges, which is consistent with published extended X-ray absorption fine structure (EXAFS) results at similar Zn/(Zn + Fe) ratios. Hence, occlusion and surface precipitation may be excluded as possible coprecipitation mechanisms. The bulk solution Zn2+ sorption edge was fitted to both solid solution and generalized diffuse layer surface complexation models. However, a solid solution model is inconsistent with published EXAFS results that show tetrahedral polydentate Zn2+ complexes sharing apices with Fe3+octahedra.  相似文献   
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